Recent Publications
IMPACT oF Halogen Bonding ON SOLUBILITY
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Dramatically Enhanced Solubility of Halide‐Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding
Mikhail A. Kinzhalov, Mariya V. Kashina, Alexander S. Mikherdov, Ekaterina A. Mozheeva, Alexander S. Novikov, Andrey S. Smirnov, Daniil M. Ivanov, Mariya A. Kryukova, Aleksandr Yu. Ivanov, Sergej N. Smirnov, Vadim Yu. Kukushkin, and Konstantin V. Luzyanin Exceptional solvation properties of diiodomethane and its inertness towards organometallics make this solvent a good candidate for NMR solvent-of-choice, in particular, for the acquisition of insensitive spins. Better solvation properties of diiodomethane were associated with formation of the uniquely strong solvent-(metal complex) halogen bonding. Angew. Chem. Int. Ed. 2018, 130, 12967–12971. DOI: 10.1002/ange.201807642 https://doi.org/10.1002/ange.201807642 |
VISIBLE LIGHT PHOTOCATALYSIS
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Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts
Jack C. Gee, Beth A. Fuller, Hannah-Marie Lockett, Gita Sedghi, Craig M. Robertson, and Konstantin V. Luzyanin Platinum–[diaminocarbene] complexes work as transition-metal photocatalysts for the hydrosilylation of alkynes under blue light irradiation. Chem. Commun., 2018, 9450–9453. DOI: 10.1039/C8CC04287J http://dx.doi.org/10.1039/C8CC04287J |
Platinum-[ADC] catalysts for hydrosilylation
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Platinum Complexes with Chelating Acyclic Aminocarbene Ligands Work as Catalysts for Hydrosilylation of Alkynes
Rogério S. Chay, Bruno G. M. Rocha, Armando J. L. Pombeiro, Vadim Yu. Kukushkin, and Konstantin V. Luzyanin We prepared and evaluated the catalytic properties of platinum complexes containing chelating acyclic aminocarbene species in the hydrosilylation of terminal and internal alkynes with hydrosilanes. ACS Omega, 2018, 3, 863–871. DOI: 10.1021/acsomega.7b01688 http://dx.doi.org/10.1021/acsomega.7b01688 |
Exclusive high-temperature cross-linking catalysts
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Iridium(III)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers
Regina M. Islamova, Mikhail V. Dobrynin, Andrey V. Vlasov, Anzhelika A. Eremina,Mikhail A. Kinzhalov, Ilya E. Kolesnikov, Andrey A. Zolotarev, Eleonora A. Masloborodova, and Konstantin V. Luzyanin Iridium(III) cross-linking catalysts for silicones show a unique temperature-curing profile and lead to thermally resistant and luminescent silicone rubbers. Catal. Sci. Technol. 2017, 7, 5843–5846. DOI: 10.1039/C7CY02013A http://dx.doi.org/10.1039/C7CY02013A |
